Unit
1 (Sample Exm1)
Practice Exam Timberlake |
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Unit 2 (Sample Exm2)
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Stoichiometry
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Stoiciometry Key.
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Unit 3 (Sample Exam3)
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Exm3 Key.
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Unit 4 (Sample Exam4)
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Practice Exam Tro
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Exm4 Key.
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| 0.01 Scientific Method |
Top |
Key |
| 1. This is perform to verify a hypothesis or theory. |
a) Hypothesis
b) Law
c) Experiment
d) Theory
e) None |
| 2.
"Conservation of Energy" is an example of a(n): |
a) Hypothesis
b) Law
c) Experiments
d) Theory
e) None |
| 3. How many experiments are required to prove a theory incorrect ? |
a)
All it takes is one.
b)
At least 5 out of 10 (50%)
c) Three quarter (3/4) ratification before a theory goes on to the Science
President for approval.
d)
If a theory is proven invalid by an experiment, the theory can still be
correct if the experimental conditions are changed.
e) No answer |
| 4. Which of the following is an example of an observation? |
a)
A gas expands when heated because the gas particle are moving faster.
b)
A balloon shrinks when taken outside on a very cold day.
c) A balloon is placed in an ice bath and then placed in a tub of hot water.
d)
A balloon will be poked with a sharp object at the end of class.
.e) No answer
|
| 5. The first step in the scientific method is ______. |
a)
Using technology
b)
making observations
c)
forming a hypothesis
d)
doing experiments
e) Proposing a theory |
| 6. Which of the following is an example of a hypothesis? |
a)
Water boils at 100°C.
b)
Seeds are planted in moist soil.
c)
Plants need sunlight to grow.
d)
The seeds sprouted 10 days after they were planted.
e) no right answer |
| 7. When a match burns, heat is evolved" is an example of |
a)
An experiment.
b)
A theory.
c)
An observation
d)
A law of nature.
e) No right answer. |
| 8. Which of the following is not a step in the scientific method? |
a)
Experiment.
b)
Theory
c)
Natural phenomenon
d)
Observation
e) all are part of the scientific method |
| 9. "All matter is made of tiny, indestructible particles called atoms" is an example of |
a)
An experiment.
b)
A theory
c)
An observation
d)
Law of nature
e) no right answer |
| 10. You noticed that there is more traffic between 8 and 9 in the morning. This would be a(n) |
a)
Observation.
b)
Hypothesis
c)
Experiment
d)
Theory
e) All of the above |
| 0.02 Chemistry and Chemicals |
Top |
Key |
| 1. Which of the following is a chemical? |
a)
Sugar
b)
Heat
c)
Light
d)
Noise
e) A wave |
| 2. Which state of matter does not take the shape of its container ? |
a)
solid
b) liquid
c)
gas
d)
vapor
e) none |
| 3. Matter changes from one form to another but is never created nor
destroyed is a statement of: |
a)
Law of conservation of energy
b)
Scientific method
c)
Uncertainty principle
d)
Law of conservation of mass
e) Proust's
Law |
| 4. What is/are substance(s) which cannot be further divided by chemical methods? |
a) mixtures
b) salt water
c) compounds
d) elements
e) all can
be divided |
| 5. Compounds and elements are both categories of: |
a)
Homogeneous mixture
b)
Heterogeneous mixture
c)
atoms
d) substances
e) all of
these |
| 6. The process in which gas turns to liquid is called: |
a)
sublimation
b)
evaporation
c)
boiling
d)
condensation
e) freezing |
| 7. Bond breaking and bond forming involves what type of change ? |
a)
intensive
b)
physical
c)
chemical
d)
personality
e) none |
| 8. In the list, which substance can be classified as a chemical? |
a)
salt
b)
sleep
c)
cold
d)
noise
e) none |
| 9. Which is important in order to accumulate knowledge about our universe? |
a)
Chemcials
b)
Technology
c)
Science
d) Mathematics
e) none |
| 10. Which in the list does not come with acceptable risk? |
a)
Nculear Technology
b)
Drug design
c)
Genome research
d)
Space exploration
e) All come with risks |
1. How may significant figures should there be in the answer to the following
problem?  |
a)
1
b)
2
c)
3
d)
4
e) none |
| 2. Which one of the following measurements contains the fewest number of significant
figures? |
a) 0.01003 mm
b)
100360 mL
c)
1300 kg
d)
1.00 • 10-4 g
e) all are
equal |
| 3. The numerator and the denominator of a conversion factor is related by: |
a)
both numbers are equivalent to each other.
b)
both must have the same units
c)
when divided by each other it yields zero
d)
both must have metric units.
e) none |
| 4. For a pharmacist dispensing pills, it is often easier to weight the medication
to be dispensed rather than to count the individual pill. If a single pill
weighs 0.65 g and the pharmacist weigh out 15.6 g of pills, how many pills
have been dispensed? |
a)
10 pills
b)
16 pills
c)
24 pills
d)
50 pills
e) none |
| 5. A nurse must administer the appropriate dosage of atropine sulfate
to a 165-lb male patient. The dosage on the label of a bottle of atropine
sulfate tablets reads 20 mg for every kilogram of body weight. If each
tablet contains 0.5 grams of atropine sulfate, how many tablets are needed
to give the correct dose to the patient? |
a)
half tablet
b)
1 tablet
c)
two tablets
d) three
tablets
e) none |
| 6. In a Gap in France, you decide to try on a pair of French
jeans. What does a waist measurement of 52 cm correspond to in inches ? |
a) 43 in
b) 32 in
c) 20.
in
d) 130 in
e) none |
| 7. The prescribed injection of a drug is 0.17 oz. If the syringe measures
volume in cubic centimeters, to what mark would you draw the drug? (29.6
mL = 1 oz) |
a)
0.17 cc
b)
5.7•10-3 cc
c)
5.0 cc
d)
29 cc
e) not enough
info. |
| 8.
The daily dosage of ampicillin for treating an ear infection is 100. mg
per kilogram of body weight. What is the dosage for a 22-lb. baby
with an ear infection? |
a)
1.0 mg
b) 1.0
g
c)
5.0 g
d)
500 mg
e) none |
| 9. Which is equal to a nanometer ? |
a)
100 Å
b)
1•10-9 m
c)
1•109 m
d)
1•107 cm
e) none |
| 10. In which of the following is the metric unit paired with its correct abbreviation? |
a)
microgram and mg
b)
milliliter and mL
c)
centimeter and km
d)
gram and gm
e) none |
| 11. Which one of the following measurements contains the most number of significant
figures? |
a)
0.01003 g
b)
100360 g
c)
100000 g
d)
10.0 •10-3 g
e) none |
| 12. Which is not an SI Unit? |
a)
gram
b)
mole
c)
sec
d)
kilogram
e) none |
| 13. Which is not an English unit? |
a) Liter
b)
pound
c)
yard
d)
ton
e) all are English units |
| 14.. Which is a derived unit ? |
a)
seconds
b)
mole
c)
calorie
d)
kilogram
e) none |
| 15.
"m" is the unit prefix for: |
a)
mile
b)
mole
c)
meter
d)
mass
e) none |
| 16.
A student calculatess a poblem on her calculator and the number 1570.2691
is shown on the display. If there are actually four significant figures,
how should she show the final answer ? |
a)
1570
b)
1570.3
c)
1.570 •10-3
d)
1.570•103
e) none |
| 17. Which measurement is the largest ? |
a)
300 K
b)
Boiling point of water
c)
250°F
d)
75°C
e) all equal |
| 18. What is the number of significant figures that should be reported
for the mass of a sample which is obtained by taking the difference between
the mass of a sample plus beaker (125.260 g) and the mass of the beaker
(124.5805 g) ? |
a)
6
b)
5
c)
4
d)
3
e) all equal |
| 19. Which of the following is the largest mass? |
a)
4.1•10-6 Kg
b)
22 g
c)
8.2•10-9 ng
d)
3•103 mg
e) all equal |
| 20. In which of the following is the metric unit paired with its correct abbreviation? |
a)
microgram and mg
b)
milliliter and mL
c)
centimeter and km
d)
gram and gm
e) none |
| 21.How many centimeters are there in 57.0 in? |
a)
22 cm
b)
0.0445 cm
c)
145 cm
d)
22.4 cm
e) 140 cm |
| 22. The measurement 0.0000043 m, expressed correctly using scientific notation, is |
a)
4.3 e-7 m
b)
4.3 e-6 m
c)
4.3 e 6 m
d)
0.43 e-5 m
e) 4.3 m |
| 23. Which of the following is the smallest ? |
a)
4.0 e-6
b)
4.0 e-8
c)
4.0 e-2
d)
1.0 e15
e) 4.0 e-12 |
| 24. Which of the following conversion factors is a measured number? |
a)
10 cm/dm
b)
12 in/ft
c)
16 oz/lb
d)
25 miles/gallon
e) 12 eggs/dozen |
| 25. Which of the following numbers contains the designated CORRECT number of significant figures? |
a)
0.04300 5 significant figures
b) 0.00302 2 significant figures
c) 156000 3 significant figures
d)
1.04 2 significant figures
e) 3.0650 4 significant figures |
| 26. A researcher needed three samples of sodium chloride solution, each with a volume of 0.03510 mL. The total volume needed should be reported as |
a)
0.105 mL
b)
0.0105 mL
c) 0.10 mL
d)
0.1053 mL
e) 0.1100 mL |
| 27. The correct answer for the addition of 7.5 g + 2.26 g + 1.311 g + 2 g is |
a)
13.071 g
b)
13 g
c)
13.0 g
d)
10 g
e) 13.1 g |
| 28. Which of the following is the largest unit? |
a)
millimeter
b) micrometer
c) meter
d)
decimeter
e) kilometer |
| 29. The cubic centimeter (cm3 or cc) has the same volume as a |
a)
cubic inch
b)
cubic liter
c)
milliliter
d)
centimeter
e) cubic decimeter |
| 30. A conversion factor set up correctly to convert 15 inches to centimeter is |
a)
100 cm / 1 m
b)
1 inch / 2.54 cm
c)
1 cm / 10 mm
d)
2.54 cm / 1 inch
e) 10 cm / 1 inch |
| 1.02 Density and Specific Gravity |
Top |
Key |
| 1. A patient provided a 5.000 cm3 urine specimen which weighed
5.125 grams. What is the specific gravity of the urine? |
a)
1.035
b)
0.975
c)
1.025
d)
1.000
e) none |
| 2. Tequila has a density of 0.78 g / mL. What mass of Tequila will fill
a 2.0 fluid ounce shot glass? (29.6 mL = 1 liquid ounce) |
a)
4.6•10-6 Kg
b) 46 g
c)
8.2 •106 µg
d)
3•103 mg
e) none |
| 3.
Calculate the volume that 3.41 grams of liquid will occupy if it has a
specific gravity of 1.025 ? |
a)
3.40mL
b)
3.45mL
c)
3.50mL
d)
3.33mL
e) none |
| 4. Density of a substance may be classified as |
a) Physical property
b) Chemical property
c) Molecular weight
d) Volume
e) none |
| 5. Which statement about water is true: |
a) 8 grams of water is more dense that 4 grams of water.
b) 8 grams of water has the same density as 4 grams of water.
c) 8 grams of water is less dense that 4 grams of water.
d) 8 grams of water contains the same moles as 4 grams of water.
e) none
of these statement is true. |
| 6. The specific gravity of a solution is 1.18. Its density is |
a) 11.8 g / mL
b) 0.118 g / mL
c) 0.847 g / mL
d) 1.18 g / mL
e) 1.2 g / mL |
| 7. Diamond has a density of 3.52 g / mL. What is the volume in cubic centimeter of a diamond with a mass of 15.1 g? |
a) 4.3 g cc
b) 4.29 cc
c) 0.233 cc
d) 53 cc
e) 53.2 cc |
| 8. Mercury has a specific gravity of 13.6. How many milliliter of mercury have a mass of 0.35 kg? |
a) 0.0257 mL
b) 0.026 mL
c) 25.7 mL
d) 26 mL
e) 4760 mL |
| 9. A nugget of gold with a mass of 521 g is added to 50.0 mL of water. The water level rises to a volume of 77.0 mL. What is the density of the gold? |
a) 10.4 g / mL
b) 6.77 g / mL
c) 1.00 g / mL
d) 0.0518 g / mL
e) 19.3 g / mL |
| 10. Which one of the following substances will float in gasoline, which has a denstiy of0.66 g/mL? |
a) table salt (density = 2.16 g/ml)
b) balsa wood (density = 0.16 g/ml)
c) sugar (density = 1.59 g/ml)
d) aluminum (density = 2.70 g/ml)
e) mercury (density = 13.6 g/ml) |
| 1. Which of the following is a property of a solid? |
a) It takes the shape of the container.
b) It fills the volume of the container.
c) The particles move at a rapid rate.
d) The interactions between its particles are very weak.
e) The particles have fixed positions and are very close together. |
| 2. Which of the following is a physical property of both liquids and gases. |
a) has its own shape.
b) has a definite volume.
c) has strong interactions between its particles
d) has randomly arranged particles
e) has large spaces between molecule |
| 3. The physical state(s) present when a substance is melting is (are) |
a) solid
b) liquid
c) gas
d) solid + liquid
e) liquid + gas |
| 4. The formation of a gas resulting from the escape of high-energy particles from the surface of a liquid is known as |
a) evaporation
b) deposition
c) boiling
d) melting
e) sublimation |
| 5. When a solid is converted directly to a gas, the change of state is called |
a) freezing
b) melting
c) boiling
d) condensation
e) sublimation |
| 6. Which of the following does NOT involve a change of state? |
a) melting ice
b) freezing water
c) vaporization of alcohol
d) sublimation of dry ice
e) pouring water in a thermost |
| 7. Helium is a(n) |
a) compound
b) heterogeneous mixture
c) element
d) homogeneous mixture
e) electron |
| 8. The primary substances of which all other things are composed are |
a) molecules
b) compounds
c) elements
d) electrons
e) protons |
| 9. Which of the following is a physical change? |
a) Baking a cake
b) Dry ice subliming
c) Fermenting grapes to produce wine
d) digesting a meal
e) a tomato ripening |
| 10. Which of the following would NOT be a physical change? |
a) freezing water to make ice cubes
b) tearing a piece of aluminum foil
c) boiling water for soup
d) burning gasoline in a lawnmower
e) melting gold to make jewelry |
| 2.02 Energy and Heating Cooling Curve |
Top |
Key |
| 1. The energy associated with the motion of particles in a substance is called |
a) temperature
b) electrical energy
c) heat
d) chemical energy
e) potential energy |
| 2. The phrase "ability to do work" is a definition of |
a) specific heat
b) energy
c) calorie
d) heating
e) cooling |
| 3. The energy stored in the chemical bonds of a carbohydrate molecule is |
a) specific heat.
b) kinetic energy.
c) potential energy.
d) work.
e) a calorie. |
| 4. In which of the following would the particles move most rapidly? |
a) ice at -20 °C
b) water at 20 °C
c) steam at 110 °C
d) boiling water
e) ice at 0 °C |
| 5. A patient has a temperature of 38.5 °C. What is the temperature in degrees Fahrenheit? |
a) 70.5 °F
b) 311 °F
c) 126.9 °F
d) 101.3 °F
e) 11.7 °F |
| 6. How many calories are required to convert 17 g of ice at 0.0 °C to liquid water at 32.0 °C? The heat of fusion of water is 80. cal/g. |
a) 43 000 cal
b) 540 cal
c) 1900 cal
d) 1400 cal
e) 80. cal |
| 7. How many calories are required to raise the temperature of a 35.0 g sample of iron from 25 °C to 35 °C? Iron has a specific heat of 0.108 cal/g °C. |
a) 38 cal
b) 1.1 cal
c) 3.8 cal
d) 93 cal
e) 170 cal |
| 8. The number of calories needed to raise the temperature of 32 g of water from 12 °C to 54 °C is |
a) 384 cal.
b) 1300 cal
c) 1.3 cal
d) 1700 cal
e) 0.76 cal |
| 9. A kilocalorie of heat is required to raise the temperature of |
a) 1 g of water from 14 °C to 15 °C.
b) 1 g of water by 10 °C.
c) 10 g of water by 10 °C.
d) 100 g of water by 10 °C.
e) 100 g of water by 100 °C. |
| 10. How many calories are required to increase the temperature of 13 g of alcohol from 11 °C to 23 °C? The specific heat of alcohol is 0.59 cal/g °C. |
a) 83 cal
b) 0.63 cal
c) 170 cal
d) 0.54 cal
e) 92 cal |
| 11) For the heating cooling curve shown, which letter labels the line segment
that corresponds to pure solid ?
|
 |
| 12. For 1 gram of water
at 1 atm, which process requires the greatest amount of energy ? |
a) To raise the temperature
of water from -20°C to -1°
b) To raise the temperature
of water from 20°C to 100°C
c) To melt ice to liquid water
at 0°C
d) To
boil liquid water to vapor steam at 100°C
e) none |
| 17. The heat of vaporization
for water is 540 cal / g and the heat of fusion for water is 80 cal/ g.
How much energy is required to take 5.0 grams of ice at 0°C to 100°C
liquid water ? |
a) 180 cal
b) 500 cal
c) 900
cal
d) 3600 cal
e) none |
| 1. A 2.5 g sample of french fries is placed in a calorimeter with 500.0 g of water at an initial temperature of 21 °C. After combustion of the french fries, the water has a temperature of
48 °C. What is the caloric value (kcal/g) of the french fries? |
a) 14 kcal / g
b) 11 kcal / g
c) 0.14 kcal / g
d) 4.2 kcal / g
e) 5.4 kcal / g |
| 2. A potato contains 20 g of carbohydrate. If carbohydrate has a caloric value of 4 kcal/g, how many kcal are obtained from the carbohydrate in the potato? |
a) 5 kcal
b) 20 kcal
c) 40 kcal
d) 60 kcal
e) 80 kcal |
| 3. A cheeseburger from a fast food restaurant contains 19 g of fat, 20 g of carbohydrate, and
28 g of protein. How many kcal of energy does the cheeseburger contain? (The accepted caloric values for foods are 4.0 kcal/g for carbohydrate, 9 kcal/g for fat, and 4 kcal/g for protein.) Report the answer to 2 significant figures. |
a) 70 kcal
b) 360 kcal
c) 17 kcal
d) 630 kcal
e) 280 kcal |
| 4. A serving of fish contains 50 g of protein and 4 g of fat. If protein has a caloric value of
4.0 kcal/g and fat has 9.1 kcal/g, how many kcal are in the serving? |
a) 240 kcal
b) 54.0 kcal
c) 470 kcal
d) 220 kcal
e) 486 kcal |
| 5. A diet has a total caloric intake of 1400 kcal. The diet consists of 50.% carbohydrate, 35% protein, and 15% fat. The number of kcal of protein in the diet is |
a) 700 kcal
b) 1200 kcal
c) 210 kcal
d) 460 kcal
e) 490 kcal |
| 6. One cup of kidney beans contains 15 g of protein, 1 g of fat, and 42 g of carbohydrate. How many kilocalories, to two significant figures, does this sample contain? |
a) 60 kcal
b) 88 kcal
c) 230 kcal
d) 240 kcal
e) 520 kcal |
| 7. The dietary calorie (Cal) is equal to |
a) 1000 kcal
b) 1000 cal
c) 100 cal
d) 10 cal
e) 1 cal |
| 8. What is the energy content, in kJ and kcal, for a piece of chocolate cake that contains 34 g of carbohydrate, 10 g of fat, and 5 g of protein? Round the answers of kJ and kcal to the tens place. |
a) 196 kcal
b) 580 Kcal
c) 140 kcal
d) 250 kcal
e) 1050 kcal |
| 9. A 2.3-g sample of butter, a fat, is placed in a calorimeter containing 1900 g of water at an initial temperature of 17 °C. After the complete combustion of the butter, the water has a temperature of 28 °C. Assume that the energy absorbed by the calorimeter is negligible. What is the energy value (kcal/g) and (kJ/g) of butter? |
a) 9.1 kcal / g
b) 21 kcal / g
c) 87 kcal / g
d) 38 kcal / g
e) no right answer |
| 10. Suppose you go out to dinner, and you order the prime rib (24 g protein, 0 carbohydrate, 10 g fat), a baked potato with no goodies (2 g protein, 26 g carbohydrate, 0 g fat), a serving of broccoli (5 g protein, 10 g carbohydrate, 5 g fats), black coffee (0 g protein, 1 g carbohyudrate, 0 g fat), and a piece of carrot cake with creame cheese icing (5 g protein, 53 g carbohydrate, 30 g fat). How many Calories did you have for dinner? |
a) 171 Cal
b) 684 Cal
c) 1344 Cal
d) 909 Cal
e) No right answer |
| 1.
The fact that vitamin C extracted from rosehips and vitamin C prepared
in the lab is the same substance is a statement of the: |
a) Law of Immutability of the Elements
b) Law
of definite proportions
c) Law of Conservation of mass
d) Law of Conservation of Energye) none of
these |
| 2.
The atom is the fundamental building block of matter. Which individual
did not directly contribute to Dalton's Atomic Theory of the atom ? |
a)
Lavoisier
b)
Proust
c)
Dalton
d)
Democritus
e) Rutherford |
| 3.
Which part of the atom was characterized by R. Millikan? |
a)
Nucleus
b)
Neutron
c)
Charge
d)
protons
e) electrons |
| 4. Whose research explained the orgins of the atomic line spectrum for hydrogen
? |
a)
Dalton
b)
Thomson
c)
Rutherford
d) Bohr
e) Schrodinger |
| 5. Which element is found in its diatomic form in nature? (i.e., H2 is a diatomic molecule) |
a)
helium
b)
lithium
c) nitrogen
d)
sulfur
e) none |
| 6. Two atoms of the same element which have different mass numbers are called: |
a) sisters
b)
brothers
c)
daughters
d) isotopes
e)
none |
| 7.
A neutral subatomic particle: |
a) protons
b) neutrons
c)
electrons
d)
orbital
e)
none |
| 8.
An 14C and 15N+ have different number
of: |
a) protons
b)
neutrons
c)
electrons
d)
orbital
e)
none |
| 9. The number of protons in the nucleus of an atom is called the ____ ____
for the atom. |
a)
mass number
b)
family number
c)
electron number
d) atomic number
e) periodic
table |
| 10. The sum of neutrons and protons in the nucleus of an atom is the ____ ____
for the particular atom. |
a)
atomic number
b) mass number
c)
isotope number
d)
number of mole
e) valence
number |
| 11.
Carbon-14 (14C) is used to date artifacts. The total number
of protons, electrons and neutrons in this atom is: |
a)
18
b) 20
c)
24
d)
26
e) none |
| 12. What information cannot be determine from the following atomic nomenclature: 15P |
a)
Z
b)
A
c)
# electrons
d)
identity
e) all
can be determined |
| 13.
The atomic mass of chlorine (Cl) is given in the periodic table as 35.453,
yet no single atom of chlorine has a mass of 35.433 amu. Which
statement explains why the atomic mass of chlorine according to the periodic
table is 35.453 ? |
a)
This mass represent the total mass of the proton, neutron and electron
for 35Cl
b) This
mass is the weighted average of all the isotopes of the chlorine atom.
c)
This mass is incorrect and should be changed.
d)
At the atomic level even the mass is quantized.
e) None of
these statement is correct. |
| 14. How many electrons will calcium lose in order to combine with oxygen? |
a)
20
b)
8
c) 2
d)
1
e) none |
| 15. In order to form negative ions from neutral atoms: |
a) electrons
must be gained
b)
electrons must be lost
c)
protons must be gained
d)
protons must be lost
e) none |
| 16. He argued that electrons moved in circular orbits around the nucleus much
like planets orbit around the sun. |
a)
Rutherford
b) Bohr
c)
Einstein
d)
Thomson
e) none |
| 17. An isotope of oxygen with 9 neutrons will have a value of A equal to: |
a) 6
b)
8
c)
16
d) 17
e) none |
| 18. Isotope of the same atom have different number of what subatomic particle
? |
a)
electrons
b)
protons
c) neutrons
d)
photon
e) none |
| 19. He argued that electrons have wave-like properties. |
a) de
Broglie
b)
Heisenberg
c)
Bohr
d)
Planck
e) none |
| 20. Which has the lowest energy ? |
a) radio-waves
b)
microwave
c)
infrared
d)
ultraviolet light
e) none |
| 21. An anion of oxygen with 9 neutrons and 9 electrons will have a charge of |
a) + 9
b)
-2
c) +1
d) -1
e) no of these |
| 22.
Which photon has the highest energy? |
a) 800 nm
b) 500 nm photon
c) Orange photon
d) UV
photon
e) energy
of light is constant |
| 23. Atomic line spectrum of the atom has its origins from |
a) electrons
relaxing down to the ground state.
b) electrons being excited to a higher energy state.
c) electron tunneling.
d) uncertainty principle.
e) This phenomena
cannot be explain by current theories. |
| 24. Complete the following table |
|
i)
|
?
|
?
|
209Bi3-
|
3-
|
?
|
?
|
?
|
|
ii)
|
?
|
?
|
?
|
?
|
111
|
75
|
73
|
|
iii)
|
?
|
?
|
?
|
2-
|
45
|
?
|
36
|
|
iv)
|
?
|
210
|
?
|
0
|
126
|
?
|
?
|
|
v)
|
79
|
198
|
?
|
?
|
?
|
?
|
76
|
|
vi)
|
?
|
?
|
14C-3
|
?
|
?
|
?
|
?
|
|
vii)
|
?
|
?
|
?Mg?
|
?
|
13
|
?
|
10
|
|
25. State which individual (from selection) is responsible for the following:
i)
First conceptualize the atom.
ii) Though that matter was composed of earth, water, wind and fire.
iii)
Proposed the "Plum-Pudding Model Theory".
iv)
Performed the Oil drop experiment.
v) Proposed
the "Law of Conservation of Matter". |
| a) Thomson |
b)
Millikan |
c)
Zeno |
d)
Lavoisier, |
e)
Boyle |
| ab) Rutherford |
ac)
Democritus |
ad)
Lewis |
ae)
Bohr |
bc)
Proust |
| bd) Empedocles |
be)
Dalton |
cd)
Bohr |
cd)
Heisenberg |
de)
Plamck |
| 1. An element with one valence electrons in its p-orbital is |
a)
Mg
b)
Na
c)
Cl
d) Al
e) none |
| 2. How many valence electrons does the phosphorus atom have? |
a)
7
b) 5
c)
15
d)
31
e) none |
| 3.
Which of the following species have noble gas electron configuration? |
a)
O2-
b)
Si4+
c)
P3-
d)
N5+
e) all
have noble gas configuration |
| 4. How many total electrons are in 59Co 3+. |
a) 24
b)
27
c)
30
d)
56
e) none |
| 5. Which of the following specie has one electron in its valence shell ? |
a)
O2+
b)
Si4+
c)
P3+
d) Ne-
e) none |
| 6. The electron configuration for selenium is |
a) [K] 4s23d104p4
b) [Ar] 4s24p4
c) [Ne] 2s22p2
d) [Ar]
4s23d104p4
e) none |
| 7. The electron configuration for chlorine is |
a)
[Ne] 3s2 3p7
b) [Ar] 4s24p7
c) [Ne] 2s2 2p2
d) [Ne]
3s2 3p5
e) none |
| 8. If sodium is changed to its most stable ion, how many electrons will there
be in the 3s orbital? |
a)
1
b)
2
c)
4
d)
11
e) none |
| 9.
Electron always have different set of quantum numbers (different address)
because of: |
a)
Aufbau
b)
Hund's rule
c) Pauli
exclusion
d)
Uncertainty principle
e) none |
| 10. If sulfur is changed to its most stable ion, how many electrons will there
be in the 3p orbital? |
a)
2
b)
4
c) 6
d)
8
e) none |
| 11. Electron are placed in degenerate orbital with the same spin because of
: |
a)
Aufbau
b) Hund's
rule
c)
Pauli exclusion
d)
Uncertainty principle
e) none |
| 12.
Which one of the following sets contains species that are all isoelectronic? (Isoelectronic means having identical electron configuration). |
a) O, F, Ne
b) C4+, N3-, O2-
c) P3-,
S2-, Ar
d)
Na, Mg, A
e) none of
theses |
| 13. Which is the electron box diagram for the unstable aluminum anion Al 4-. |
Answer (d) |
| 14. Which one of the following orbital does not exist in the 3rd shell ? |
a)
s
b)
py
c)
d
d) f
e) px |
| 15. Which of the following is the correct number of valence electron for Geranium |
a)
1
b)
2
c) 4
d)
8
e) none |
| 16. How many electrons are in 193Ir ? |
a)
193
b) 77
c)
116
d)
none
e) no enough
info |
| 17. Which of the following is the correct number of valence electron for Helium. |
a)
1
b) 2
c)
4
d)
8
e) none of
these |
| Please
refer to the following diagram for the series of questions. |
 |
| 1. For a given family, which arrow corresponds to the increase of shell for
an element. |
a)
1
b)
2
c) 3
d)
4
e) None |
| 2. Which set of arrows correspond to decrease in atomic size ? |
a) 1,4
b)
3,2
c)
3,1
d)
2,4
e) None |
| 3. Elements with four electrons in its valence are found in which portion
of the periodic table? |
a)
r
b)
s
c)
t
d) u
e) None |
| 4. Which set of arrows correspond to decrease in metallic character ? |
a)
1,4
b) 3,2
c)
3,1
d)
2,4
e) None |
| 5. Which set of arrows corresponds to decreasing ionization energy? |
a) 1,4
b) 3,2
c) 3,1
d) 2,4
e) none |
| 6. Which set of arrows corresponds to decrease in electron affinity? |
a) 1,4
b) 3,2
c) 3,1
d) 2,4
e) none |
| 7.
Elements with the outer most electron configuration ns2 np1 are found in which portion of the periodic table? |
a) q
b) r
c) s
d) t
e) none |
| 8. For a given period which arrow correspond to elements with the greatest
tendency to become cations ? |
a) 1
b) 2
c) 3
d) 4
e) none |
| 9.
Within a period in the periodic table of the elements, the most nonmetallic
element is found in what row. |
a) 2nd
b) 3rd
c) 4th
d) 5th
e) all are
equal |
| 10. Which element in the VIA family is the most metallic ? |
a)
Sulfur
b)
Selenium
c)
Tellurium
d) Polonium
e) none |
| 11. Which atom below is the most paramagnetic ? |
a)
N
b)
P
c)
As
d)
Sb
e) all
are equally paramagnetic. |
| 12. What is the symbol for cobalt ? |
a) Co
b)
Ca
c)
CO
d)
C
e) none |
| 13. Iodine is part of which family? |
a)
alkali
b)
alkaline earth
c)
metalloids
d) halogens
e) none |
| 14. What is the atomic mass of Geranium according to the periodic table ? |
a)
31.0
b)
32.0
c)
69.7
d) 72.6
e) none |
| 15. Which one of the following is one of the first 36 elements ? |
a) Iron
b)
Cesium
c)
Tin
d)
Iodine
e) none |
| 16. What is the symbol for carbon.: |
a)
Co
b)
Cu
c)
Ca
d) C
e) none |
| 17.
What is the most stable charge for helium ? |
a)
+3
b)
-2
c)
-3
d)
-4
e) none
of these |
| 18. Which of the following would has the most favorable electron affinity ? |
a)
K
b)
Br
c)
Al
d) Cl
e) none |
| 19. Sodium has chemical properties most like: |
a) cesium
b)
magnesium.
c)
chlorine
d)
mercury
e) none |
| 20. This element, in the 4th period, is a transition metal in which old pennies
are made from. |
a)
zinc
d)
nickel
c)
lead
d) copper
e) none |
| 21. Which element is a metal? |
a)
chlorine
b) sodium
c)
argon
d)
sulfur
e) all are
nonmetals |
| 22. Which of the following would has the highest ionization energy? |
a)
potassium
b) boron
c)
aluminum
d)
calcium
e) all are
equal |
| 4.01 Nuclear Chemistry |
Top |
Key |
| 1. The product from the alpha decay of 23592U. |
a) 23593Np
b) 23994Pu
c) 23380Ra
d) 23190Th
e) 23692U |
| 2. The nuclear symbol of helium,42He, is also the symbol for designating a(n) |
a)
Proton
b)
neutron
c) gamma ray
d) beta particle
e) alpha particle |
| 3. The symbol 0-1e is a symbol used for a(n) |
a)
Proton
b) beta particle
c) gamma ray
d) alpha particle
e) neutron |
| 4. Which of the following types of radiation has the highest energy? |
a) α - particle
b) γ - particle
c) β - particle
d) visible light
e) all of these have the same energy |
| 5. For 8538Sr, there are |
a)
85 protons and 38 neutrons
b) 47 protons and 38 neutrons
c) 38 protons and 85 neutrons
d) 38 protons and 47 neutrons
e) 85 protons and 47 neutrons |
| 6. Which is NOT a way to minimize your exposure to radiation? |
a) staying a longer time
b)
wearing lead-lined gloves
c) wearing a lead apron
d) keeping a good distance
e) standing behind a thick concrete wall |
| 7. A nuclear equation is balanced when |
a)
the same elements are found on both sides of the equation.
b) the sum of the mass numbers and the sum of the atomic numbers of the particles and atoms are the same on both sides of the equation
c) the same particles and atoms are on both sides of the equation.
d) different particles and atoms are on both sides of the equation.
e) the charges of the particles and atoms are the same on both sides of the equation. |
| 8. The nuclear reaction shown below is an example of what type of process?
|
a)
translation
b)
fission
c) fusion
d) beta emission
e) alpha emission |
| 9. Nitrogen-17 is a beta emitter. What is the isotope produced in the radioactive decay? |
a) 186C
b) 135B
c) 187N
d) 178O
e) 139F |
| 10. What is missing in the nuclear reaction shown below?
|
a) a neutron
b) 137B
c) 147N
d) 135N
e) 137N |
| 11. When aluminum-27 is bombarded with a neutron, a gamma ray is emitted. What radioactive isotope is produced? |
a)
silicon-27
b) aluminum-28
c) silicon-28
d) magnesium-27
e) magnesium-28 |
| 12. Sodium-24 has a half-life of 15 hours. How many hours is three half-lives. |
a) 45 hours
b)
60 hours
c) 30 hours
d) 15 hours
e) 7.5 hours |
| 13. Iodine-123, which is used for diagnostic imaging in the thyroid, has a half-life of 13 hours. If 50.0 mg of I-123 were prepared at 8:00 A.M. on Monday, how many mg remain at 10:00 A.M. on the following day? |
a) 12.5 mg
b)
6.25 mg
c) 3.13 mg
d) 25.0 mg
e) 50.0 mg |
| 14. A sample of cerium-141 for a diagnostic test was dissolved in saline solution to an activity of 4.5 millicuries/mL. If the patient undergoing the test needs a dose of 10 millicuries, how much of the solution should be injected into the patient? |
a)
4.5 mL
b)
22 mL
c) 0.45 mL
d) 45 mL
e) '2.2 mL |
| 15. The recommended dosage of I-131 for a test is 4.2 microcuries per kg of body weight. How many millicuries should be given to a 55 kg patient? (1 mCi = 1000 μCi) |
a)
230 millicuries
b)
760 millicuries
c) 0.076 millicuries
d) 0.23 millicuries
e) 13.8 millicuries |
| 16. Which of the following is powered by nuclear energy
? |
a) Amtrack trains
b) submarines
c) automobiles
d) your brain
e) none |
| 17. Nuclear energy in this country is in the form of |
a) Potential Energy
b) Activiation Energy
c) Nuclear Fission
d) Nuclear Fusion
e) none |
| 18. Which isotope is used to determine the age of artifacts
(i.e., Shroud of Turin) ? |
a) Polonium-214
b) Iodine-131
c) Carbon-14
d) Uranium-238
e) none |
| 19. The following are produce by radioactive processes. Which one has mass but no charge? |
a) alpha particle
b) beta particle
c) gamma radiation
d) neutron
e) position |
| 20. The number of half-lives neeeded for a radiactive element to
decay to one-eight of its original activity is (choose the nearest number): |
a) 2
b) 3
c) 5
d) 10
e) none |
| 21. Which is a common household item which emits ionizing
radiation. |
a) television
b) coffee maker
c) toaster
d) bathroom scale
e) none |
| 22. Alpha radiation is actually a dication of |
a) carbon
b) calcium
c) helium
d) hydrogen
e) none |
| 23. Which type of radiation will completely go through your
body and requires lead or concrete walls to stop its progress. |
a) alpha
b) beta
c) gamma
d) radiowave
e) none |
| 24. What is the name of the former USSR where the most disasterous
nuclear accident occurred |
a) Moscow
b) Linengrade
c) Chernobyl
d) St. Petersburg
e) Three mile island |
| 25. The closest commerical nuclear power plant to San Diego
is located |
a) Diablo
b) Three Mile Island
c) San Clemente
d) San Onofre
e) none |
| 26. In a nuclear power plant what is used to elevate
the temperature of water above 3000°F without boiling it over? |
a) catalyst
b) Pressure
c) uranium rods
d) radiation
e) large volume |
| 27. Which is a common health problem because of dangerous
radiation exposure ? |
a) Acidosis
b) a healthy tan
c) Cancer
d) greenhouse effect
e) cardiac arrest |
| 28. Electron capture transfoms 7Be into what nuclide
? |
a) 6Li
b) 8B
c) 7L
d) 6Be
e) 12C |
| 29. Identify the missiong particle in the following equation: 238U → 4He + __ |
a) 242Pu
b) 234Th
c) 242Th
d) 234U
e) none |
30. What nuclide product is necessary to balance the following
fission reaction:
238U + 1n → 3 1n + 139Ba + __ |
a) 96Br
b) 96Kr
c) 94Rb
d) 94Kr
e) 90Sr |
| 31. When 28Al emits a ß- particle
it becomes: |
a) 28Mg
b) 28Si
c) 29Si
d) 27Al
e) none |
| 32. A radioactive element has a hal-life of 1.0 hr. How
many hours will it take for the number of atoms present to decat to 1/16th of the initial value? |
a) 16
b) 8
c) 4
d) 15
e) 2.77 |
| 33. The smallest amount of radioactive material that will suppor
ta self-sustained reaction is called the: |
a) molar mass
b) moderator
c) supercritical mass
d) sub critical mass
e) critical mass |
| 34. Which of the following is NOT TRUE of nuclear fission |
a) High temp. are required for the process to occur.
b) The energy released is very large.
c) The starting materials are heavy elements
like U or Pu.
d) It happens in the hydrogen bomb.
e) The mass of the system decreases when the nuclei fuse
together. |
| 35. Give three arguments why a community would elect to build
a coal burning power plant versus a nuclear power plant? |
| |
| 5.01 Chemcial Nomenclature |
Top |
Key |
| 1. A cation has more: |
a)
e- than p+
b)
p+ than n
c)
atomic mass unit than its atom
d) p+ than e-
e) none |
| 2. Which element will combine with one atom of magnesium? |
a)
Ca
b)
Na
c)
He
d) O
e) none |
| 3.
Polar covalent are formed when the electrons involved in bonding |
a)
are transferred from one atom to the other.
b)
are equally shared between the atoms involved in bonding.
c)
are excited to a higher atomic orbital.
d) are
unequally shared between atoms involved in bonding.
e) none of
these statements are true. |
| 4. Which of the following is an example of an empirical formula ? |
a)
C4H10
b)
C6H12O6
c) Sn2Cl4
d) C5H10O4
e) none |
| 5. Which is an example of a formula unit ? |
a)
C2H5
b) Sn2O4
c) 
d)
sodium bromide
e) CaO |
| 6. Which elements when bonded to each other will from covalent bonds ? |
a)
argon & fluorine
b)
copper & carbon
c) oxygen & sulfur
d)
potassium & cesium
e) H & Na |
| 7. Which substance is most likely to possess covalent bonds? |
a) PCl3
b) KBr
c) MgF2
d)
ScCl3
e) none |
| 8. Which substance has ionic bonds? |
a) Na2O
b)
NCl3
c)
H2S
d)
CO2
e) none |
| 9 Which compound has a total of 32 valence electrons ? |
a)
hypochlorite
b)
chlorite
c)
chlorate
d) perchlorate
e) chloride |
| 10 Give the chemical name of the specie with the formula XY, where X is the
element in diamonds and Y is the element which support life? |
a) carbon
monoxide
b)
carbon dioxide
c)
carbon chloride
d)
silicon carbide
e) none |
| 11 What is the oxidation number of Sn in SnO2 ? |
a)
l
b)
2
c) 4
d)
5
e) none |
| 12.
What information about a chemical formula will always lead you to the correct
type (I, II or III) of compound. |
a)
total electrons in the anion
b)
Identity of group of the first element in the compound
c) the
family of the metal
d)
the number of valence electrons.
e) none |
| 13.
Which is the correct formula for iron(II)nitride ? |
a) Fe3N2
b)
Ir3N2
c)
Fe2N
d)
Ir(NO3)2
e) none |
| 14.
What is the oxidation number of Mn in MnO4- ? |
a) -1
b)
2
c)
3
d)
5
e) none
(+7) |
| 15.
What is the formula of the compound formed when aluminum (Al) combines
with oxygen (O)? |
a)
AlO
b)
AlO2
c) Al2 O3
d)
Al3O2
e) none |
| 16.
Which is the correct formula for dihydrogen monoxide? |
a)
O2H
b)
H(II)O
c)
2HO
d) H2O
e) none |
| 17.
What is the correct name for (NH4)2CO3 ? |
a)
ammonia tricarbonate
b) ammonium
carbonate
c)
ammonia (II) carbonate
d)
diammonium monocarbonatee) none |
| 18.
Which of the following has a "+2" cation in its formula ? |
a)
CO
b)
Pb(SO4)2
c)
(NH4)2S
d) SnO
e) none |
| 19.
Which of one of the following is not polyatomic ion? |
a) oxide
b)
sulfite
c)
chlorate
d)
hydroxide
e) none |
| 20.
Which of the has a (III) in its name ? |
a)
PCl3
b)
O2F3
c) Cr(NO3)3
d)
N2S3
e) none |
| 21.Which
is the correct formula for manganese(II) nitride ? |
a)
MgN
b)
Mg2N
c)
Mg3N
d)
Mg3N2
e) none |
| 22.
Which compound has a correctly written chemical formula ? |
a)
Mg(SO3)2
b)
Fe+3(OH-)3
c)
Cd3SO3
d) (NH4)3N
e) SE2I3 |
| 23.
Which transition metal has a (I) oxidation state ? |
a) Hg2O
b)
KClO
c)
Au2(CO3)3
d)
Pb(IO4)4
e) none |
| 24.
Consider the following compounds, i -iv, below. Which statement
is true about these compounds ? |
| i)
calcium bromite |
ii)
sodium bromate |
iii)
sodium bromide |
iv)
sodium bicarbonate |
a) all the compounds are type I
b) all the anion are polyatomic
c) all anions contain the bromine atom
d) three of the four are ionic
e) none of these statements are true |
| 25. Which of the following is the correct number of valence electron for Helium
? |
a)
1
b) 2
c)
4
d)
8
e) none |
| 26. What is the most stable charge for oxygen ? |
a)
+3
b) -2
c) -3
d) -4
e) Cannot
be determine |
| 27.
Which anion, when combine with hydrogen, will form bromic acid? |
a)
Br-
b)
BrO-
c)
BrO2-
d) BrO3-
e) BrO4- |
| 28.
Which chemical formula is correctly written ? |
a) diammonium carbonate
b)
potassium(I) phosphide
c) Tin2sulfide
d) boron
trihydride
e) none |
| 29.
Which of the following will combine with one atom of tellurium |
a)
Fe (III)
b) Ir(II)
c)
V (I)
d)
Se
e) all of
these |
| 30.
What is the formula of the compound dicarbon tetrachloride? |
a)
C4Cl
b) C2Cl4
c)
CCl2
d)
C2Cl3
e) none |
Consider the
following matrix for the next few questions.
|
hyposulfite
|
sulfite
|
sulfate
|
persulfate
|
sulfide
|
|
Carbon
|
a
|
b
|
c
|
d
|
e
|
|
cadmium
|
ab
|
ac
|
ad
|
ae
|
bc
|
|
cobalt
|
bd
|
be
|
cd
|
ce
|
de
|
| 31.
Which combination is CdSO4 ? |
| 32.
If carbon is combined with one of the anion, which combination yields CS2 ? |
| 33.
Given a +3 oxidation state of this transition metal, which combination
yields M2(SO2)3 ? |
| 34.
What compound gives CoS for an oxidation state of +2 to Co ? |
| 1. What is the correct Lewis dot structure for the chlorine atom ? |
a) 
b) 
c) 
d) 
e) none |
| 2. Which of the following is a correct Lewis structure ? |
a) 
b) 
c) 
d) 
e) none |
| 3. Which is the following is the correct Lewis electron-dot formula for HCN
? |
a) 
b) 
c) 
d) 
e) none |
| 4
. Which compound has a Lewis structure in which there are three bonds
? |
a)
H2O
b)
CO2
c) NO-
d) O3
e) none |
| 5. Which chemical has seven bonds ? |
a) C2H4
b)
C2H2
c) C2H6
d)
C3H6
e) none |
| 6. How many total valence electrons are in SO32- ? |
a)
24
b)
30
c)
32
d) 26
e) none |
| 7. Which of the following specie has an odd number of electrons in its Lewis
Structure ? |
a)
ClO-
b) ClO2
c)
Cl2O
d)
ClO2-
e) none |
| 8. What is the total number of valence electrons for the Lewis structure for
an ionic specie with the formula MX, where the atom M has 20 protons and
X is found in the second period. ? |
a)
2
b)
4
c) 8
d)
28
e) none |
9.
The Lewis structure for NF3 is : What is the electronic geometry of NF3? |
a)
trigonal
b)
planar
c) pyramidal
d)
tetrahedral
e) linear |
| 5.03 Molecular Geometry |
Top |
Key |
| 1. Which arrangement is in order of increasing electronegativity ? |
a)
Cl, H, Br, C
b)
B, F, P, O
c)
Al, K, N, C
d) Sr,
Sc, Si, S
e) none |
| 2.
What is the VSEPR molecular geometry for O3 ? |
a)
trigonal
b)
pyramidal
c) bent
d)
tetrahedral
e) none |
| 3.
Consider the imaginary compound XY2. This compound is
non-polar, yet the electronegativity of X is 2.5 , whereas the electronegativity
of Y is 3.6. It stands to reason that the molecular shape of this
molecule is : |
a)
bent
b)
trigonal
c) linear
d)
pyramidal
e) not enough
info. |
| 4.
Which of one of the following is polar ? |
a)
H2
b) BH3
c) HCO
d)
BeF2
e) none |
| 5.
What is the molecular geometry of hypophosphite, PO23. ? |
a)
tetrahedral
b)trigonal
c)
linear
d) bent
e) none |
| 6.
What is the molecular geometry of the H2CO ? |
a)
bent
b) trigonal
c)
pyramidal
d)
linear
e) none |
| 7.
Which compound below is nonpolar ? |
a) CO2
b)
CH2F2
c)
NO2-
d)
H2S
e) none |
8. In the molecule CSO, , the overall electron density is distorted toward which atom?. |
a)
Carbon
b)
sulfur
c) oxygen
d)
no net distortion
e) none |
| 9. What is the molecular geometry of the sulfate ion ? |
a)
bent
b)
trigonal
c) tetrahedral
d)
pyramidal
e) none |
| 10.
What is the molecular geometry of sulfur dioxide ? |
a) bent
b)
trigonal
c)
tetrahedral
d)
pyramidal
e) none |
| 11.
What is the molecular geometry of the F2CS ? |
a)
bent
b) trigonal
c) pyramidal
d)
lineare) none |
| 12.
Which type III compound is also takes a linear geometry ? |
a)
SO2
b) CS2
c)
CaCl2
d)
SnO2
e) CuOH |
| 13.
Which compound below is polar ? |
a)
CO2
b)
C2F2
c)
CS2
d) H2S
e) none |
| 14.
What is the molecular geometry of the nitrate ion, NO3- ? |
a)
tetrahedral
b) trigonal
c)
linear
d)
bent
e) none |
| 15.
Which is most like to dissolve to an appreciable extent in water ? |
a)
CO2
b)
CH4
c) NH3
d)
N2
e) none |
| 16.
Sodium nitrate is considered a strong electrolyte because it- |
a)
contains a metal and a nonmetal.
b)
is needed for good health.
c) conducts
electricity.
d)
releases heat when water is added
e) is
an ionic compound. |
| 17. Which set has compounds that have the same electronic geometry (AEn)
? |
a)
CO2 & H2O
b) CCl4 & NH4+
c)
O3 & N3-
d)
SCl2 & BeH2
e) none |
| 5.04 Intermolecular Forces |
Top |
Key |
| 1. Which of the following
indicates very strong intermolecular forces of attraction in a liquid? |
a) Low boiling point
b) low melting point
c) low surface tension
d) high
vapor pressure
e) none |
| 2. Which of the molecules
shown below is capable of dissolving I2 (a nonpolar compound)
to an appreciable extent? |
a) PH3
b) CCl4
c) HBr
d) HCN
e) none |
| 3. Which of the following would
have a boiling point lower than SiCl4 ? |
a) LiCl
b) CCl4
c) SiBr4
d) GeCl4
e) none |
| 4. Which of the following
covalent molecules can hydrogen bond to water? |
a) nitrogen N2
b) methane CH4
c) ethanol
C2H5OH
d) chlorine Cl2
e) none |
| 5. Which of the following
is not a special property of water ? |
a) water molecules is capable
of H-bonding.
b) water is a polar
molecule.
c) the solid state (ice) is
less dense than the liquid form.
d) water
has a very low surface tension.
e) all the same |
| 6. Which of the molecules
shown has its intermolecular forces dominated by dispersion forces ? |
a) N2
b) CH3OH
c) H2O
d) NH3
e) none |
| 7. Which of the following
forces between atoms, ions or molecules is the strongest ? |
a) Covalent bonds
b) dipole-dipole force
c) hydrogen bond
d) London dispersion
force
e) none |
| 8. Which substance is
the least polarizabe ? |
a) Cl2
b) Xe
c) Kr
d) Br2
e) all the same |
| 9. The evaporation rate
of a given liquid will increase if : |
a) the liquid is moved to
a container in which its surface is very much larger
b) the volume of the liquid
is increase.
c) the volume of a vapor phase
is increased.
d) the
temperature is increased.
e) a more volatile liquid is added to the given liquid. |
| 10. The sublimation of
solid carbon dioxide, dry ice, is an example of: |
a) evaporation
b) physical property
c) chemical property
d) chemical change
e) none of these |
| 11. The carbon tetrachloride molecule, CCl4, is |
a) a polar molecule with polar bonds.
b) a nonpolar molecule with nonpolar bonds.
c) a polar molecule with nonpolar bonds.
d) a polar molecule with ionic bonds.
e) a nonpolar molecule with polar bonds |
| 12. The main type of interaction between molecules of hydrogen ( H2 ) are |
a) ionic bonds
b) dispersion forces
c) hydrogen bonds.
d) polar covalent
e) dipole-dipole |
| 6.01 Balancing Chemical Reactions |
Top |
Key |
| 1. Predict the
missing product in the following unbalance equation. Mg + N2 → ___ |
a) MgN
b) Mg3N
c) Mg2N
d) Mg3N2
e) none |
| 2. Which reaction
below gives a balance equation such that the sum of the coefficient equals
10 ? |
a) HCl (aq) + Cr (s) → CrCl3(s) + H2 (g)
b) FeCl3(s) +
Na2CO3(aq) → Fe2(CO3)3 (aq) + NaCl (aq)
c) PbS (aq) + H2O2(aq) → PbSO4(aq) + H2O (l)
d) C4H10 (l) + O2 (g) → CO2 (g) + H2O (l)
e) none |
| 3. Which equation below violates the law of conservation
of mass? |
a) 2CaCO(3) → 2CO2 + 2CaCO
b) 4H2 + 2O2) → 4H2O
c) 2HCl + Na2OH → HOH + 2NaCl
d) AgCl + NaNO3 →
AgCl + NaNO3
e) all of these |
| 4. Which reaction below gives a balance equation
such that the sum of the coefficients of the reactant equals 5 ? |
a) C5H10
(l) + O2 (g) → CO2 (g) + H2O (l)
b) CoCl3(s)+
CaCO3(aq) → Co2(CO3)3(aq) + CaCl2(aq)
c) PbSO4(aq) + H2O (l) → PbS(aq) + H2O2 (aq)
d) HBr(aq) + Cr (s) → CrBr3(s) + H2 (g)
e) none |
| 5. In a combustion reaction which is not a product
? |
a) oxygen
b) water
c) carbon dioxide
d) energy
e) all of these |
6. What is the
sum of the coefficient on H2O and H3PO3 in the balanced equation ?
__PCl3 + __H2O → __H3PO3 + __HCl |
a) 2
b) 3
c) 4
d) 6
e) none |
7. What is the
sum of the coefficient on Fe2S3 and HCl for
the balanced equation ?
__FeCl3 + __H2S → __Fe2S3 + __HCl |
a) 23
b) 5
c) 6
d) 7
e) none |
8. What is the
sum of all the coefficients after the following equation is balanced ?
__CO2 + __H2O → __C6H12O6 + __O2 |
a) 4
b) 24
c) 18
d) 19
e) none |
9. What is the sum of the coefficient when balancing
the following equation ?
__ FeCl3 + __ AgNO3 →
__ Fe(NO3)3 + __ AgCl |
a) 3
b) 4
c) 6
d) 8
e) none |
| 10. When barium
nitrate is combine with potassium sulfate a precipitate forms. What is
the likely identity of the precipitate ? (Hint, determine if chemical formula
is correct). |
a) Ba(NO3)2
b) KSO4
c) BaSO4
d) K2NO3
e) none |
| 6.02 Moles and Stoichiometry |
Top |
Key |
| 1. What is the
formula weight of beryllium sulfate? |
a) 41.0
b) 57.0
c) 105.0
d) 106.8
e) no answer |
| 2. How many moles
of chlorine atoms are there in 1 mole of Ca(ClO)2• CaCl2? |
a) 1
b) 2
c) 4
d) 35.5
e) none |
| 3. Which contain
the smallest mass ? |
a) 1.25 mol Na
b) 0.236
mol Mg
c) 0.11 mol Ba
d) 3.75•1022 atoms Se
e) all the same |
| 4. State the total number of atoms in a single molecule
of C7H5NO3S (saccharin). |
a) 2.93•1026
b) 1.02•1025
c) 17
d) 183.1
e) none |
| 5. What is the
mass of a thimble of water which contains 4.0•1021 molecules? |
a) 1.2 g
b) 1.2•10-8 g
c) 12 g
d) 0.12
g
e) none |
| 6. State the
mass of oxygen atoms (grams) in a mole of C7H5NO3S
(saccharin): |
a) 16 g
b) 48
g
c) 183.0
d) 32 g
e) none |
| 7. What is the number of oxygen atoms in 20 ammonium
dichromate, (NH4)2Cr2O7,
formula unit ? |
a) 70
b) 1.20•1025
c) 140
d) 20
e) none |
| 8. What is the
atomic mass of an element that weights 2.66•10-23 g |
a) 16.0
g/mol
b) 55.9 g/mol
c) 12.0 g/mol
d) 4.42•10-47 g/mol
e) none |
| 9. The compound
MgSO4 is called Epson salts. What mass is needed to prepare
a bath with 5.000 mole of Epsom salt ? |
a) 0.04156g
b) 24.06g
c) 120.3g
d) 601.5
g
e) none |
| 10. How many moles
of H atom are there in 18.0 moles of formaldehyde H2CO ? |
a) 1.00
b) 2.0
c) 18.0
d) 36.0
e) none |
| 11. What is the mass of a single sulfur atom (32.01
g/mol) ? |
a) 32.01 g
b) 16.0 g
c) 5.33•10-23 g
d) 4.42•10-47g
e) none |
| 12. How many molecules of TNT, C7H5N3O6 (Mol. Wt. = 227.0 g/mol ) are in 5.8 moles of TNT ? |
a) 3.5•1024
b) 21
c) 1.3•103
d) 121
e) none |
| 13. What is the mass of oxygen in 18.0 moles of formaldehyde
H2CO ? |
a) 540 g
b) 288 g
c) 18.0 g
d) 576 g
e) none |
| 14. Calculate
the number of moles of aspirin, C9H8O4,
in a 8.0 g tablet. |
a) 4.4•10-2
b) 4.6•10-3
c) 4.9
d) 0.022
e) none |
| 15. A typical cholesterol deposit in an artery might
have a mass of 3.9 mg of cholesterol (C27H46O).
How many molecules of cholesterol are in this mass ? |
a) 1.01•10-2
b) 1.01•10-5
c) 6.1•1018
d) 6.1•1021
e) none |
| 16. Which chemical
has a molar mass of 180 g/mol ? |
a) KI
b) NH3
c) C2Cl6
d) C6H12O6
e) none |
17. How many grams
of N2 will be required to completely react with 9.3 g of H2 in the reaction:
N2 + 3H2 → 2NH3 |
a) 1.3•102
b) 2.0
c) 43
d) 3.9•102
e) none |
| 18. If it takes
three wheels, one body, and two handle grips to produce a tricycle, how
many tricycles can be produce from twenty wheels, twenty bodies and forty
handle grips ? |
a) 6
b) 6.67
c) 20
d) cannot be determined
e) none |
19. How many moles
of Al are needed to react with 2.5 mol of Fe2O3 in
the equation:
2 Al + Fe2O3 → Al2O3 + 2 Fe |
a) 135
b) 2.0
c) 5.0
d) 1.25
e) no answer |
20. The number
of grams of K2O produced from the oxidation of 4.0 grams of
K in the reaction:
K (s) + O2 (g) → K2O (g) |
a) 4.8
g
b) 4.0 g
c) 9.4 g
d) 6.3 g
e) none |
| 21. If it takes 1 plate, four forks, and three spoons,
two knife and one napkin and to produce one table setting, how many table
setting can be produce from 58 plate, 27 forks, and 33 spoons, 26 knife
and 58 napkin ? |
a) 11
b) 6
c) 13
d) cannot be determined
e) none |
| 22. In the reaction : NaOH
+ H2SO4 → Na2SO4 + 2H2O How many moles of water is formed when 2.0 moles of H2SO4 reacts with exces NaoOH ? |
a) 1
b) 2
c) 4
d) 6
e) none |
| 23. Calcium carbonate (MWt = 100.0 g/mol) is
common chalk. How many grams of CO2 is produce if 100
grams of chalk is decomposed to CaO and CO2 ? |
a) 100 g
b) 50.0 g
c) 44 g
d) 56 g
e) none |
24. Which is the limiting reagent when 25.0 g of
NH3 reacts with 25.0 g of O2 according to the
reaction:
4 NH3 + 3O2 → 2N2
+ 6H2O ? |
a) NH3
b) O2
c) N2
d) H2O
e) none |
25. How many grams of NF3 (71.0 g/mol)
is required to produce 1.0•1024 molecules of N2 ?
The equation is: 2 NF3 → N2
+ 3F2 |
a) 51.6 g
b) 2.0 g
c) 2.5•103 g
d) 7.3•103 g
e) none |
| 26. What is the
actual yield in a chemical reaction if the percent yield is 87% for a theoretical
yield of 55.4 g ? |
a) 40.8 g
b) 50.8 g
c) 48.2 g
d) 47.6 g
e) none |
| 27. What is the
percentage yield if the theoretical yield in a reaction is 60.4 grams but
only 51.7 grams was actually recovered ? |
a) 1.17 %
b) 85.6
%
c) 8.56 %
d) 117 %
e) none |
28. Zinc will react with a solution of hydrochloric acid
to produce hydrogen gas according to the reaction :
Zn + 2 HCl → ZnCl2 + H2
How many dozen hydrochloric acid will react with 10 dozen of zinc ? 1doz = 12 |
a) 240 doz
b) 2 doz
c) 10 doz
d) 20 doz
e) none |
29. Tungsten W, is produced from tungsten (VI) oxide according
to the following unbalanced equation:
__WO3 (s) + __H2 (g) → __W(s) + __H2O.
How many grams of tungsten metal could you produce from 36.0 g of tungsten(VI)
oxide?
MWt: WO3= 231.9 g/mol, W = 183.9 g/mol , H2 = 2.0 g/mol, H2O = 18.0 g/mol |
a) 183.9 g
b) 45.4 g
c) 28.5 g
d) 1.59 g
e) none |
30. Use the
balance equation shown to answer the questions below.
Na(s) +
Cl2(g) → 2 NaCl(s)
a) How many moles of Cl2 are needed to react with 3.5 mol of Na ?
b) What mass of NaCl are produced
from 1.75 mol of Cl2?
c) How many mole of Cl2 is needed to produce 117 grams of NaCl ?
d) What mass of Na is needed to
produce 73.11 g of NaCl ? |
Answers
a) 1.75 mol of Cl2
b) 3.5 g of NaCl
c) 1.0 mol of Cl2
d) 28.7 g of Na |
| 1. Atmospheric pressure
is the lowest at which location ? |
a) Denver,
Colorado
b) San Diego, CA
c) Death Valley, CA
d) Manhattan, NY
e) all the same |
| 2. Which law best describe
the mechanism of breathing ? |
a) Avogadro
b) Gay-Lussac
c) Boyle
d) Charles
e) Medical |
3. Which postulate from
the kinetic molecular theory explains why gas fill their container. |
a) Gases
are in random motion
b) kinetic energy of gas is
directly proportional to the temperature
c) Volume of the gas is negligible
d) As the pressure increase,
the volume decrease.
e) none of these are valid explanation |
| 4. Which of the following is NOT part of the kinetic theory of gases? |
a) A gas is composed of very small particles.
b) Gas particles move rapidly.
c) There is very little empty space in a gas.
d) Gas particles do not attract or repel one another.
e) Gas particles move faster when the temperature increases. |
| 5. The force of gas particles against the walls of a container is called |
a) Pressure
b) Volume
c) Demsity
d) Quantityu of gas
e) Temperature |
| 6. The boiling point of water at sea level is 100 °C. At higher altitudes, the boiling point of water will be |
a) lower, because temperatures are lower.
b) higher, because there are fewer water molecules in the air.
c) higher, because the altitude is greater.
d) lower, because the atmospheric pressure is lower.
e) the same, because water always boils at 100 °C. |
7. The balloon is put into a chamber whose pressure is less than the atmospheric pressure and at atmospheric temperature.
|
a) A
b) B
c) C
d) Not enough information
e) No right answer |
8. The temperature is changed from 50 °C to -150 °C at constant pressure.
|
a) A
b) B
c) C
d) Not enough information
e) No right answer |
| 9. The pressure exerted by a gas on its container is directly proportional to |
a) the mass of the individual gas molecules.
b) the number of molecules of gas in the sample.
c) the centigrade temperature of the gas.
d) the Fahrenheit temperature of the gas.
e) the volume of the container. |
| 10. A barometer is a device for measuring __________. |
a) atmospheric pressure
b) blood pressure
c) gas pressure in a container
d) gas pressure in the lung
e) vapor pressure |
| 7.02 Gas Calculations and Stoichiometry |
Top |
Key |
| 1. If a 1.5 liter flask
at 1 atm and 25ºC contains 7.0 mol of carbon dioxide gas, how many
moles of nitrogen will the same size flask contain if the temperature and
pressure remain constant? |
a) 4.5 mol
b) 1 mole
c) 7.0
mol
d) 14.0 mol
e) Cannot be determine |
| 2. What is the temperature
of a balloon which contains 0.25 mol of gas, with a volume of 11.2 liters,
and a pressure of 380 mm Hg. [1 atm = 760 mm Hg, R = 0.0821 (L•atm/ mol•K).] |
a) 1653 K
b) 273 °C
c) 273
K
d) 0 K
e) none of these |
| 3. Determine the volume
(L) of 0.250 mol of gas at 545 mmHg and 15.0°C. |
a) 1.08•10-2 L
b) 0.429 L
c) 8.24
L
d) No answer provided
e) none of these |
| 4. What is the molecular
weight of a gas which weighs 6.40 g, at STP and occupies a volume of 4.48
liters. |
a) 32.0
g/mol
b) 16 g/mol
c) 1.43 g/mol
d) 0.700 g/mol
e) Cannot be determined |
| 5. An anesthesiologist
administers a gas at 20° C to a patient whose body is 37° C.
What is the change in volume (L) of a 1.20 L sample of gas as it
goes from room temperature to body temperature? . |
a) 1.27
L
b) 0.788 L
c) 2.22 L
d) 1.20 L
e) No answer provided |
| 6. Which combination
of changes would produce no change in the pressure of a gas. |
| |
Volume
|
Temperature
|
number of moles
|
| a) |
double
|
no change
|
half
|
|
b)
|
half
|
no change
|
double
|
|
c)
|
double
|
double
|
no change
|
|
d)
|
no change
|
half
|
half
|
|
e)
|
no change
|
double
|
no change
|
|
| 7. What is the pressure
in a 10.0 L container that contains 0.240 mol of N2 and 0.260
mol of O2 at a T = 27°C ? |
a) 2.66 atm
b) 14.8 atm
c) 1.23
atm
d) 7.40 atm
e) none of these |
| 9. What unit of temperature is used in gas law calculations? |
a) degrees Fahrenheit
b) degrees Celsius
c) Kelvin
d) either degrees Celsius or degrees Fahrenheit
e) either degrees Celsius or Kelvin |
| 10. The volume of a sample of gas, initially at 25 °C, increases from 158 mL to 450. mL. What is the final temperature of the sample of gas, if the pressure in the container is kept constant? |
a) 8.8 °C
b) 71 °C
c) -168 °C
d) 105 °C
e) 576 °C |
| 11. In Gay-Lussac's Law, the pressure of a gas increases due to an increase in temperature because |
a) the molecules strike the walls of the container less often.
b) the molecules strike the walls of the container more often.
c) the molecules get bigger.
d) there is a decrease in the volume of the container.
e) there is an increase in the number of gas particles. |
| 12. A gas sample contains 4.0 g of CH4 and 2.0 g of He. What is the volume of the sample at STP? |
a) 17 L
b) 30. L
c) 5.6 L
d) 11 L
e) 130 L |
| 13. A diver exhales a bubble with a volume of 250 mL at a pressure of 2.4 atm and a temperature of 15 °C. What is the volume of the bubble when it reaches the surface where the pressure is 1.0 atm and the temperature is 27 °C? |
a) 1100 mL
b) 580 mL
c) 110 mL
d) 100 mL
e) 630 mL |
| 14. A diver exhales a bubble with a volume of 250 mL at a pressure of 2.4 atm and a temperature of 15 °C. How many gas particles are in this bubble? |
a) 0.25 gas particles
b) 6.02 x 1023 gas particles
c) 1.5 x 1022 gas particles
d) 90 gas particles
e) 2.9 x 1026 gas particles |
| 15. A cyclopropane-oxygen mixture is used as an anesthetic. If the partial pressure of cyclopropane in the mixture is 330 mmHg and the partial pressure of the oxygen is 1.0 atm, what is the total pressure of the mixture in torr? |
a) 330 torr
b) 1100 torr
c) 430 torr
d) 760 torr
e) 1.4 torr |
16. When 25.0 g of Zn reacts, how many L of H2 gas are formed at STP?
Zn(s) + 2HCl(aq) → H2 (g) + ZnCl2 (aq) |
a) 4.28 L
b) 0.0171 L
c) 8.56 L
d) 22.4 L
e) 0.382 L |
17. How many L of O2 gas at STP, are needed to react with 15.0 g of Na?
4Na(s) + O2 (g) → 2Na2O(s) |
a) 14.6 L
b) 7.30 L
c) 22.4 L
d) 32.0 L
e) 3.65 L |
| 18. If atmospheric pressure on a certain day is 749 mmHg, what is the partial pressure of nitrogen, given that nitrogen is about 78% of the atmosphere? |
a) 760 mm Hg
b) 749 mm Hg
c) 600 mm Hg
d) 584 mm Hg
e) 165 mm Hg |
| 19. A tank contains a mixture of helium, neon, and argon gases. If the total pressure in the tank is 490 mmHg and the partial pressures of helium and argon are 215 mmHg and 102 mmHg, respectively, what is the partial pressure of neon? |
a) 0.228 mmHg
b) 603 mmHg
c) 377 mmHg
d) 807 mmHg
e) 173 mmHg |
| 20. A 1.20-L container contains 1.10 g of an unknown gas at STP. What is the molecular weight of the unknown gas? |
a) 20.5 g/mole
b) 1.32 g/mole
c) 0.917 g/mole
d) 22.4 g/mole
e) 1.10 g/mole |
| 8.01 Solution Concepts |
Top |
Key |
| 1. Indicate which of
the following properties is not characteristic of a solution. |
a) uniform and homogeneous
b) cannot separate with filter
paper
c) solution
may be cloudy at times
d) components do not separate
upon standing
e) all are properties of solutions |
| 2. The solubility of
a solid solute in water will not depend on what factor ? |
a) temperature
b) size of solute particles
c) polarity of solute
d) pressure
e) all of these |
| 3. A solution that contains more solute (in the dissolve form)
than normal is called: |
a) unsaturated
b) saturated
c) supersaturated
d) too strong
e) none of these |
| 4. Which substance below is a nonelectrolyte ? |
a) vinegar
b) graphite
c) potassium iodide
d) NH4Cl
e) all are electrolyte |
| 5. Sucrose (sugar) is considered a nonelectrolyte because it |
a) only partially breaks up
in water.
b) does
not separate into ions in water.
c) is a covalent compound.
d) dissociates completely
in water to give charge ions.
e) is a nonpolar compound. |
| 6. Sodium chloride
is added to 100 ml of water. This mixture is called a _1_, the water is the_2_
and the salt is the _3_ |
| |
1
|
2
|
3
|
| a) |
solute
|
solvent
|
solution
|
|
b)
|
solvent
|
solution
|
solute
|
|
c)
|
solution
|
solute
|
solvent
|
|
d)
|
solution
|
solvent
|
solute
|
|
e)
|
solution
|
solute
|
solute
|
|
| 7. Which compound below is a strong electrolyte |
a) distilled water
b) acetic acid (vinegar)
c) table sugar
d) table
salt
e) none of these |
| 8. The solubility of
a gas increases with: |
a) increase temp
b) increase pressure
c) decrease pressure
d) all of these
e) solubility is constant |
| 9. When KCl dissolves in water |
a) the Cl- ions are attracted to dissolved K+ ions.
b) the Cl- ions are attracted to the partially negative oxygen atoms of the water molecule.
c) the K+ ions are attracted to Cl- ions on the KCl crystal.
d) the K+ ions are attracted to the partially positive hydrogen atoms of the water molecule.
e) the Cl- ions are attracted to dissolved K+ ions. |
| 10. An equivalent is |
a) the amount of ion that has a 1+ charge.
b) the amount of ion that carries 1 mole of electrical charge.
c) 1 mole of any ion.
d) 1 mole of an ionic compound.
e) the amount of ion that has a 1- charge. |
| 11. How many equivalents are present in 5.0 g of Al3+? |
a) 0.56 Eq
b) 15 Eq
c) 0.19 Eq.
d) 0.37 Eq.
e) 3 Eq. |
| 12. An intravenous replacement solution contains 4.0 mEq/L of Ca2+ ions. How many grams of Ca2+ are in 3.0 L of the solution? |
a) 0.24 g
b) 0.80 g
c) 0.40 g
d) 240 g
e) 4.0 g |
| 13. Methanol, CH3OH, can be classified as a __________. |
a) weak electrolyte
b) soilid
c) strong electrolyte
d) nonelectrolyte
e) gas |
| 14. An increase in the temperature of a solution usually |
a) increases the solubility of a solid solute in the solution.
b) increases the boiling point.
c) increases the solubility of a gas in the solution.
d) decreases the solubility of a solid solute in the solution.
e) decreases the solubility of a liquid solute in the solution. |
| 15. When solutions of NaCl and AgNO3 are mixed. |
a) a precipitate of AgCl2 forms.
b) precipitate of NaNO3 and AgCl form.
c) no precipitate forms.
d) a precipitate of NaNO3 forms.
e) =a precipitate of AgCl forms. |
| 1. The concentration of NaCl in blood serum is 0.14 M. What volume
of blood serum contains 4.0 g NaCl ? |
a) 490
ml
b) 240 ml
c) 555 ml
d) 38.5 ml
e) No answer provided |
| 2. What is the concentration
of a solution if 10.0 ml of a 3.00 molar solution of NaOH is diluted
to a 500.0ml |
a) 0.600M
b)150. M
c) 1670 M
d) 0.300M
e) cannot be determined |
| 3. What is the concentration, in m/m%, of a solution prepared from 50.0 g NaCl and 150.0 g of water? |
a) 0.250%
b) 33.3%
c) 40.0%
d) 3.00%
e) 25.0% |
| 4. Rubbing alcohol is 70.% isopropyl alcohol by volume. How many mL of isopropyl alcohol are in a 1 pint (473 mL) container? |
a) 70. mL
b) 0.15 mL
c) 680 mL
d) 470 mL
e) 330 mL |
| 5. How many grams of glucose are needed to prepare 400. mL of a 2.0%(m/v) glucose solution? |
a) 800. g
b) 0.0050 g
c) 8.0 g
d) 2.0. g
e) 2 00. g |
| 6. What volume (mL) of a 15% (m/v) NaOH solution contains 120 g NaOH? |
a) 18 mL
b) 8.0 e2 mL
c) 0.13 mL
d) 120 mL
e) 0.13 mL |
| 7. What is the molarity of a solution that contains 17 g of NH3 in 0.50 L of solution? |
a) 34 M
b) 0.50 M
c) 2.0 M
d) 0.029 M
e) 1.0 M |
| 8. When 200. mL of water are added to 100. mL of 12% KCl solution the final concentration of KCl is (Assume the volumes add. |
a) 12%
b) 4.0%
c) 36%
d) 6.0%
e) 8.0% |
| 9. How many moles of CaCl2 are in 250 mL of a 3.0 M of CaCl2 solution? |
a) 750 moles
b) 0.75 moles
c) 3.0 moles
d) 83 moles
e) 1.3 moles |
| 10. What is the new mass/volume (m/v)% of a KOH solution that is prepared by diluting 110 mL of a 6% (m/v) KOH solution to 330 mL? |
a) 2%
b) 1%
c) 6%
d) 1.2%
e) 1.8% |
| 8.03 Solution and Stoichiometrty |
Top |
Key |
| 1. Use the reaction: 2AgNO3 (aq) + H2SO4 (aq) ? Ag2SO4 (aq) + 2H2O(l) What volume of 0.123 M AgNO3 (aq) is needed to form 0.657 g of Ag2SO4 (s) ? |
a) 34.2 L
b) 17.1 mL
c) 34.2 mL
d) 10.7 mL
e) 53.4 mL |
2. Zinc reacts with HCl to produce ZnCl2 and hydrogen gas H2:
Zn (s) + 2HCl(aq) → ZnCl2 (aq)+ H2(g)
How many liters of a 1.50 M HCl solution completely react with 5.32 g of zinc?
? |
| |
1. The activation energy for Reaction A is 10.0 kJ and that of Reaction B
is 100 kJ.Which statement is always true? |
a)
Reaction A is already at equilibrium
b)
Reaction B releases 100 kJ of energy
c)
Reaction A and B are both endothermic
d)
Reaction A and B are both exothermic
e) Reaction
A is faster than reaction B |
|
2. A method to decrease the production of NOCl in the reaction:
2 NO2(g) +Cl2(g) → 2 NOCl2 (g) is to : |
a)
increase Cl2
b)
decrease pressure of NOCl
c)
increase NO gas
d) removeCl2
e)
none |
|
Consider
the following reaction profile diagram for the next series of questions
3. According to the above reaction profile diagram, the reverse reaction:C → A, is a(n) ______process. |
a) endothermic
b)
exothermic
c)
spontaneous
d) catalytic
e)
none |
|
Consider
the following reaction profile diagram for the next series of questions
4. According to the above reaction profile diagram, the forward reaction:A → C, is a(n) ______process. |
a)
endothermic
b) exothermic
c)
spontaneous
d)
catalytic
e)
none |
|
| 5. A catalyst introduce to this reaction will not affect which pair
of arrows? |
a)
w, x
b)
x, y
c)
y, z
d) w,y
e)
none |
|
6. If the energy of the reactant is 40 kJ, the product is 10 kJ and the Eact is
50 kJ for the reaction profile diagram. What is the transition state
energy ? |
a)
30 kJ
b)
80 kJ
c) 90
kJ
d)
100 kJ
e)
none |
|
7. The reaction of nitric oxide with ozone produces200
kJ of energy.
NO(g) + O3 (g) → NO2 (g) + O2 (g) Since energy is produced,
this reaction is |
a) exothermic
b)
endothermic
c)
at equilibrium
d)
a fast reaction
e)
none |
|
| 8. Which is not a factor affecting reaction rates ? |
a)
concentration of reactant
b)
shaking or agitation..
c)
temperature of the reaction.
d)
addition of catalyst.
e) all
of these are factors |
|
| 9.02 Equilibrium and LeChatelier |
Top |
Key |
1. Identify the equation that would give the equilibrium expression  |
a) CO2 + 2 H2 O → CH4 + 2O2
b) 2 CH4 + 4 O2 → 2CO2 + 4H2O
c) CH4
+ 2O2 → CO2 + 2H2 O
d) CH4 + 2H2O → CO2 + 2O2
e) CO2 + H4O2 → CH4 + 2O2 |
|
2. Indicate the mass action expression for the following reaction:
2X(g)
+ Y (g) → 3W(g) + V(g) |
|
3. Calculate the equilibrium
constant for N2 (aq)+ 3 H2 (aq) → 2 NH3 (aq), the equilibrium concentration are: [N2]=
0.5M, [H2] = 1.0 M, [NH3] = 2.0 M. |
a)
0.25
b)
4
c) 8
d)
16
e)
none |
|
| 4. Consider the following diagram for the next several questions
What is the minimum time before equilibrium is established
for the above reaction ? |
a)
1/3 min
b)
1 min
c)
2 min
d) 4
min
e)
none |
|
| 5. Consider the following diagram for the next several questions
After 5 minutes, which is the dominate species in the reaction |
a) A
b)
B
c) C
d)
cannot be determine
e)
none
|
|
6. The heat of reaction for the conversion
of graphite to diamond is small, in fact, this reaction takes place only under
extremely high temperatures and pressure.
0.45 Kcal + C(graphite) → C(diamond)
Which statement is true concerning why this
reaction doesn’t readily take place.? |
a) This
reaction has a very high activation energy.
b)
This reaction has a small equilibrium constant.
c)
This reaction is endothermic.
d)
This reaction leads to a higher entropy.
e)
none of these are true. |
| 7. Which will not alter the speed of a reaction? |
a)
catalyst
b)
temperature
c)
stirring rxn
d)
adding more product
e) all
will affect the speed
|
| 8. Sodium hydroxide is considered a strong base because it. |
a)
neutralizes acid and water
b) dissociates
completely (100%) in water to give hydroxide ions
c)
contains sodium
d)
is used frequently to unclog drain pipes
e)
none |
|
9. Consider the following reaction: C(s) + CO2 (g) + 41.3 Kcal → 2CO(g) ,
which process below will increase the production of CO(g) ? |
a)
the amount of carbon is decrease
b)
CO2 is continuously decreased ?
c)
The temperature is decreased
d) more
energy is added
e)
Some oxygen is added |
|
10. The following chemical reaction is at equilibrium: 2NO + O2 → 2NO2
Calculate the equilibrium constant (Keq) if the concentrations of reactants and products are 1.26•10-10 M for NO, 2.28•10-3 M for O2, and 9.32•10-6M for NO2 |
a)
2.40•10-12
b)
3.28•10-7
c)
2.61•10-17
d) 2.40•1012
e)
none |
11. Given this reaction at equilibrium: N2O4 → 2NO2,
calculate the equilibrium constant (Keq) If the concentrations of N2O4 and NO2 are 0.0238 M and 0.196 M, respectively. |
a)
8.34
b)
3.46
c)
0.621
d) 1.61
e)
none |
| 12. Given this reaction at equilibrium: A B, in which the concentration of B > A at equilibrium. Which statement is true about Keq? |
a) Keq > 1
b)
Keq = 1
c)
Keq<1
d)
Keq = 0
e)
none |
|
| 10.01 Concepts in Acid Base |
Top |
Key |
| 1. The smog from car emmission leads to acid rain because of what chemical ? |
a) SO2
b) NO2
c) CFCs
d) NO
e) none of these |
| 2. Which compound below is diprotic ? |
a) H2O
b) HCl
c) H2SO4
d) HNO3
e) None of these |
| 3. If a small amount of lye is added to neutral water whcih contains the phenolphthalein indicator, the solution will |
a)
remain pink
b) remain
clear
c) turn
pink from clear
d) turn clear
from pink
e) turn blue
from pink |
| 4. What is the conjugate base of the bicarbonate ion, HCO3- ? |
a) H2O
b) HCO3-
c) H2CO3
d) CO3-2
e) CO2 |
| 5. Vinegar is a household product that has a pH ___ 7.0 . |
a) smaller
than
b) greater
than
c) equal to
d) equal to zero
e) can't determine |
| 6. Which chemical is poured into a buret in a titration experiment ? |
a) analyte
b) indicator
c) titrant
d) water
e) conjugate |
| 7. Human blood is naturally |
a) neutral
b) basic
c) acidic
d) radioactive
e) toxic |
| 8. Which is not a buffer system in the blood ? |
a) phosphate
b) carbonate
c) proteins
d) hydroxide
e) all can be buffer systems in the blood |
| 9. Which equation is used to solve buffer type problems ? |
a) Ideal gas
law
b) diimension analysis
c) Henderson-Hasselback
d) Haber reaction
e) stoichiometry |
| 10. Sodium hydroxide is considered a strong base because it |
a)
neutralizes acid and water
b) dissociates completely (100%) in water to give hydroxide ions
c)
contains sodium
d)
is used frequently to unclog drain pipes
e)
none |
|
11. Consider the following reaction: H2O(l) + H2O(l) + E → H3O+(aq) + OH-(aq) ,
what will happen to Kw when heat is added to water ? |
a) Kw increases
b) Kw decreases
c) Kw does not change
d)
Kw = 0
e)
none |
| 12. A base are substances that have a____ taste and turn litmus ____. |
a)
sour, blue
b)
bitter, red
c)
sour, red
d) bitter, blue
e)
none |
|
| 13. In the eastern USA, most acid rain is due to the atmospheric presence of |
a) SO2
b) NO2
c) CFCs
d) NO
e) none |
| 14. The auto-ionization of water has an equilibrium constant equal to |
a) 7
b) 14
c) 1.0•10-7
d) 1•10-14
e) none |
| 15. Acids are substances that have a____ taste and turn litmus ____ |
a) sour, blue
b) bitter, red
c) sour, red
d) bitter, blue
e) none |
| 16. Which compound below is amphoteric? |
a) H2O
b) HCl
c) H2SO4
d) HNO3
e) none |
| 17. Which of the following does NOT represetn a conjugate acid-base pair? |
a)
H3O+ / H2O
b)
HCN / CN-
c)
HCl / Cl-
d) HC2H3O2 / OH-
e)
all are conjugate pairs |
|
| 18. Addition of a strong acid to a solution with a pH equal to 8.0 does not change the pH of the solution. It stands to reason that the original solution: |
a) contains a strong acid
b) contains a strong base
c) is a buffer
d) taste sour
e) none |
| 19. Which of the following solutions would you expect not to conduct electricity? |
a) NaOH in water
b) O2 in water
c) HCl in water
d) acetic acid in water
e) all will conduct |
| 20. The compound HA is an acid that is soluble in water. Which beaker below shows HA behaving as a strong acid in water? |
a) 
b) 
c) 
d) 
e) all of these are weak acids |
| 21. Rain water is generally considered to have a pH around |
a) 2.5
b) 4.5
c) 7.5
d) 6.2
e) no right answer given |
| 22. Which compound below is triprotic ? |
a) H2O
b) HCl
c) H2SO4
d) HNO3
e) none |
| 23. The Henderson-Hasselbalch equation is used to calculate which of the following: |
a) whether an acid is a strong or weak acid
b) whether a reaction between an acid and base will go to completion
c) the extent of acidosis or alkalosis in the blood
d) the ratio of concentration of the
acid and its conjugate base to be used in preparing a buffer solution at
the desired pH
e)
none of these are true.
|
| 24. What is cause of the acidic rain water if you were in the island of Fiji ? |
a) H2SO4
b) HNO3
c) H2CO3
d) H2O
e) none |
| 25. Which of the following could be considered an Arrhenius acid? |
a) HCl
b) CH3COOH
c) NH4+
d) HNO3
e) all
of these |
| 26. Why is HF in water considered a weakly acidic solution, while HCl and HBr in water are considered strongly acidic solutions? |
a)
HF does not dissolve in water
b)
HF is generally not very reactive
c) HF
only partially dissociates into ions in water
d)
HF has a weak conjugate base, F-
e)
both c and d are correc |
| 27. In a neutralization reaction, which chemical is always produced? |
a) CO2
b)
bubbles
c) O2
d) H2O
e) none |
| 28. Which chemical below is not a strong acid? |
a)
hydrochloric acid
b)
nitric acid
c)
sulfuric acid
d)
perchloric acid
e) acetic
acid |
| 29. A cause of metabolic acidosis would be: |
a) starvation
b)
excessive throw-up
c)
heavy breathing
d)
hysteria
e)
none |
| 30. Which of the reaction below proceeds from left to right ? i.e., Ka >> 1 |
a) H2O + CH3COO- → OH- + CH3COOH
b) H3O+ + I- → H2O + HI
c) 2 H2O → OH- + H3O+
d) H2O + HNO3 → H3O+ + NO3-
e) none of these |
| 31. Which common product below is the most acidic? |
a) vinegar
b) acid rain
c) Pepsi
d) battery acid
e) milk |
| 32. Explain how buffer systems regulate the pH of your blood. |
|
| 10.02 pH and Calculations |
Top |
Key |
| 1. What is the pH of a solution that is 1 10-3 M HCl ? |
a) -3
b) 3
c) 11
d) 0.001 M
e) no right answer |
| 2. What is the pOH whose pH = 9 ? |
a) 1
x 10-9
b) 5
c) -5
d) 1
x 10-5
e) no right answer |
| 3. The pKa values for four acids are 2.6, 3.6, 4.9 and 5.2. The weakest acid is the one with pKa value of: |
a) 2.6
b) 5.2
c) 4.9
d) 3.6
e) no right answer |
| 4. Calculate the pH of a 0.10 M solution of Ca(OH)2 |
a) 13.30
b) 13.00
c) 0.20
d) 0.10
e) none |
| 5. The pH of a 1•0-10 M KOH solution is |
a) -4
b) 4
c) 10
d) -10
e) no right answer |
| 6. At room temperature a solution with a H+ concentration of 1•0-5 M will have an OH- concentration of: |
a) 5
b) 0.00001
c) -5
d) 1•10-9
e) none |
| 7. Basic (i.e., NH3) solutions will generally have pH ___ 7.0. |
a)
smaller than
b) greater
than
c)
equal to
d)
precisely equal to
e)
can't determine |
|
| 8. How many moles of hydroxides are formed for each mole of calcium hydroxide
dissolved in water? |
a) 74 mol
b) 1 mol
c) 2
mol
d) 148 mol
e) no right answer |
| 9. The Ka value for lactic acid is 1.4 • 10-4 M. Is this a weaker or stronger acid than HF with a pKa of
5.74: |
a) stronger
b) weaker
c) same
strength
d) none
e) need more information |
| 10. If natural rain water has an acid concentration of [H3O] + = 2•10-6 M. The pH is ___? |
a) 5.7<
b) 7.0
c) - 5.7
d) - 6
e) none |
| 11. The pKa values for four acids are 2.6, 3.6, 4.9 and 5.2. The strongest conjugate base will have a pKb value of: |
a) 2.6
b) 5.2
c) 8.8
d) 11.4
e) none |
| 12. The Ka value for lactic acid is 1.4•10-4 M. The pKa value is: |
a) 4.1
b) 4.6
c) 3.9
d) 3.1
e) none |
| 13. The pH of an aqueous solution is
9.35. What is the pOH? |
a) -4.65
b) 0.971
c) 4.65
d) 0.668
e) none |
| 14. How many equivalence of hydroxide in 1 mole of Ca(OH)2 ? |
a) 74.1
b) 37.0
c) 1
d) 2
e) none |
| 15. A 10.0 ml solution of NaOH requires 20.0 ml of 2.0 N H2SO4 for phenolphthalein to turns from pink to colorless. What is the concentration of the original NaOH solution ? |
a) 1.0 N
b) 2.0 N
c) 4.0 N<
e) none |
| 16. A solution with a [H3O+] of 0.00001 M has a pH of: |
a) 4.0
b) 5.0
c) 7.0
d) 10.0
e) none |
| 17. A substance that changes color at a certain pH is called |
a) a buffer
b) an indicator
c) a conjugate acid
d) a pH meter
e) a salt |
| 18. A 0.050 L solution of H2SO4 requires 200.0 ml of 4.0 N NaOH for phenolphthalein to turns from pink to colorless. What is the molarity of the original H2SO4 solution ? |
a)
4.0 M
b)
1.6•104 M
c)
16.0 M
d) 8.0M
e)
none |
|